Some quick details about Spiderman 3's controls on the Wii:
Analog stick of the Nunchuck is used to move Spider Man. The other buttons on the Nunchuck are used to jump and run. During fights the player can let Spider Man attack by moving the Wiimote. You can fly through New York by shooting spiderwebs, to do this you have to move the Nunchuck and Wiimote forward in turn. Catch your enemies by shooting webs at them, you can then do some special attack moves. And lots more.