Ariane 5 ECA will be able to place heavy payloads of up to 10 tonnes into geostationary transfer orbit (GTO) in comparison to the 6-tonne payloads placed into GTO by the Ariane 5 Generic launchers. The increased performance of the Ariane 5 ECA is due to two main differences:
a more powerful Vulcain-2 first stage engine developed from the Ariane 5 generic Vulcain 1 engine a cryogenic upper stage (ESCA) using the tried and tested Ariane 4 HM7B engine that made over 130 successful launches
More info at ESA